CHE 173: Mechanistic Organic Chemistry II & Lab
(1) Your final grades are posted on
Campus-Connect. Please let me know if you have any questions
or problems. Best of luck to all of you in CHE 175!
(2) The final
exams are graded and
your scores are posted below. Please see me if you're
interested in looking over your exam.
The "173-Breakfast
Club":
Thanks to all who volunteered on Saturday March 5th:
Tom Lyons, Rupal Doshi, Dana Marlowe, Sarah
Hendricks, Paul Wucka, Shannon McGinty,
Monika Zybszynska, Farah Merchant, Enes Ovcina, Elissa Johnson,
Mike Balco, Ren Ruivivar, Ty Tsang, Jennifer Skala,
and Sheena McDaniels, Sonya Morocho & Priscila Limon (not
pictured)
|
|
|
|
|
|
from Carey |
|
|
|
13.1-13.2 & 13.20 |
Introduction to spectroscopy; IR spectroscopy |
|
|
13.21-13.23 |
UV-Vis Spectroscopy and Mass Spectrometry (MS) |
|
|
13.3 |
Introduction to 1H NMR spectroscopy |
|
|
13.4-13.5 |
Intro to 1H NMR spectroscopy, cont'd through 13.5 |
|
|
|
|
|
|
13.6-13.9 |
Interpreting 1H NMR spectra |
|
|
13.10-13.13 |
Interpreting 1H NMR spectra, continued |
|
|
13.14-13.17 |
13C NMR spectroscopy |
|
|
|
|
|
|
10.1-10.4 |
Introduction to conjugation; allylic halogenation |
|
|
10.5-10.9 |
Classes, relative stabilities, bonding, and preparation
of dienes |
|
|
10.10-10.14 |
Reactions of dienes: hydrohalogenation, addition,
Diels-Alder; MO analysis |
|
|
|
Practice Quiz 3 Practice Quiz 3 Answer Key |
|
|
11.1-11.4 |
Benzene, resonance, and resonance energy |
|
|
11.5-11.9 |
Hybridization and MO analysis of benzene, nomenclature,
polycyclic aromatics, and physical properties of arenes |
|
|
11.10-11.19 |
Reactions of arenes 1: Birch reduction, FR halogenation
and oxidation of alkyl benzenes, nucleophilic substitution
in benzylic halides |
|
|
|
Practice Quiz 4 Practice Quiz 4 Answer Key |
|
|
11.21-11.22, 12.1-12.3 |
Aromatic ions and heterocyclic aromatics; Electrophilic
aromatic substitution (EAS) reactions: nitration |
|
|
12.4-12.5 |
Electrophilic aromatic substitution (EAS) reactions:
sulfonation, halogenation |
|
|
Class |
Canceled |
|
|
12.6-12.11 |
Friedel Crafts alkylation and acylation,
acylation/reduction; Rate and regioselectivity of EAS;
substituent effects |
|
|
|
Practice Quiz 5 Practice Quiz 5 Answer Key |
|
|
12.12-12.14 |
Substituent effects in EAS: activating substituents,
deactivating substituents and halogens |
|
|
12.15-12.18 |
Multiple substituent effects |
|
|
|
Practice Quiz 6 Practice Quiz 6 Answer Key |
|
|
14.1-14.7 |
Introduction to organometallic compounds, organolithium
reagents and Grignard reagents |
|
|
14.8-14.9 |
Synthesis using organometallic compounds; retrosynthetic
analysis |
|
|
14.10-14.12 |
Organo-copper, organo-zinc and other organometallic
reagents; more synthetic applications |
|
|
|
Practice Quiz 7 Practice Quiz 7 Answer Key |
|
|
15.1-15.5 |
Sources and preparation of alcohols and diols |
|
|
15.6-15.11 |
Reactions of alcohols |
|
|
15.12-15.14 |
Reactions of diols, thiols; spectroscopic analysis of
alcohols and thiols |
|
|
|
This week's quiz will consist of 5 questions/problems taken DIRECTLY from the assigned exercises from Carey's Chapter 15. |
|
|
16.1-16.8 |
Nomenclature, structure & bonding, and physical
properties of ethers, epoxides and sulfides; preparation and
reaction of ethers |
|
|
16.9-16.14 |
Preparation and reaction of epoxides |
|
|
16.15-16.18 |
Sulfides; spectroscopic analysis of ethers, epoxides and
sulfides |
|
|
|
Practice Quiz 9 |
|
|
23.1-23.9 |
Aryl halides: properties and reactivity |
|
|
24.1-24.8 |
Phenols: properties and reactivity |
|
|
24.9-24.15 |
Phenols: reactivity and analysis |
|
|
Specific Objectives |
11:45-2:00 p.m. |